(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
CAS: 380230-02-4
Molecular Formula: C36H30NO2P
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) - Names and Identifiers
| Name | (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) |
| Synonyms | (S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine |
| CAS | 380230-02-4 |
| InChIKey | LKZPDRCMCSBQFN-UIOOFZCWSA-N |
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) - Physico-chemical Properties
| Molecular Formula | C36H30NO2P |
| Molar Mass | 539.6 |
| Melting Point | 88-89°C |
| Boling Point | 710.7±63.0 °C(Predicted) |
| Specific Rotation(α) | +13.1° (c 1.01, CHCl3) |
| Appearance | Powder |
| Color | off-white |
| pKa | -0.57±0.20(Predicted) |
| Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
| Sensitive | moisture sensitive |
| Use | Chiral phosphoramidite ligands for copper-catalyzed high enantioselective conjugate addition reactions that allow the addition of dialkyl zinc to various Michael receptors. 1,2,3 can also be used for diethylzinc-mediated palladium-catalyzed polarity reversal allylation. |
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) - Risk and Safety
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. |
| WGK Germany | 3 |
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) - Reference Information
| Applications | chiral phosphoramidite ligands for copper-catalyzed Highly Enantioselective conjugate addition reactions, this reaction can add dialkyl zinc to a variety of Michael receptors. 1,2,3 can also be used for diethylzinc-mediated palladium-catalyzed polarity reversal allylation reactions. |
Last Update：2024-04-09 02:00:02
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Product Name: (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine. Visit Supplier Webpage Request for quotationCAS: 380230-02-4
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Product Name: (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Visit Supplier Webpage Request for quotationCAS: 380230-02-4
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Product Name: (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Visit Supplier Webpage Request for quotation
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(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
1-Butanone, 3-methyl-1-(2,3,5-trichloro-6-hydroxyphenyl)-
N-ME-ABZ-LYS-PRO-LEU-GLY-LEU-DAP(DNP)-ALA-ARG-NH2
N-(2,4-二溴苯)-4-氟苯甲酰胺
2-[2-(propan-2-yloxy)ethoxy]cyclooctan-1-amine
Dimethylxanthogen disulfide
2-Pyrazinecarboxylic acid, (2,2-dimethyl-1-oxopropoxy)methyl ester
丁基乙基丙烷二醇
2-(4-((4-((5-(3-METHYLTHIOPHEN-2-YL)-1H-PYRAZOL-3-YL)AMINO)QUINAZOLIN-2-YL)AMINO)PHENYL)ACETONITRILE
四乙二醇二甲基醚
1-Butanone, 3-methyl-1-(2,3,5-trichloro-6-hydroxyphenyl)-
N-ME-ABZ-LYS-PRO-LEU-GLY-LEU-DAP(DNP)-ALA-ARG-NH2
N-(2,4-二溴苯)-4-氟苯甲酰胺
2-[2-(propan-2-yloxy)ethoxy]cyclooctan-1-amine
Dimethylxanthogen disulfide
2-Pyrazinecarboxylic acid, (2,2-dimethyl-1-oxopropoxy)methyl ester
丁基乙基丙烷二醇
2-(4-((4-((5-(3-METHYLTHIOPHEN-2-YL)-1H-PYRAZOL-3-YL)AMINO)QUINAZOLIN-2-YL)AMINO)PHENYL)ACETONITRILE
四乙二醇二甲基醚